Size dependent oxygen buffering capacity of ceria nanocrystals.
نویسندگان
چکیده
The structural, chemical and electronic changes of ceria as a function of decreasing particle size have been studied: at sizes below 5 nm the total amount of reducible oxygen dramatically increases due to superoxide formation on the ceria surface, a result indicative of a size dependent oxygen buffering capacity.
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ورودعنوان ژورنال:
- Chemical communications
دوره 46 11 شماره
صفحات -
تاریخ انتشار 2010